![]() | COMMERCIAL ENGINE STANDARD PRACTICES MANUAL | Dated: 12/15/2023 |
SPM 70-21-20 CLEANING METHOD NO. 20 - FOUR-STEP ALKALINE CLEANING AND ACIDIC DESCALING (WITH INHIBITED PHOSPHORIC ACID) | ||
TASK 70-21-20-110-038 |
1 . | General. |
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A. | This cleaning method is a multiple hot-tank process that is effective in removing heat scale and oxide formation from hot-section parts of the engine. This method is recommended for cleaning nickel-based alloys prior to fluorescent penetrant inspection. |
B. | Unless specified differently, TASK 70-21-10-110-008 (70-21-10, Cleaning Method No. 10 - Four-Step Alkaline Cleaning and Acidic Descaling (Without Inhibited Phosphoric Acid)), can be used as alternative to TASK 70-21-20-110-038 (70-21-20, Cleaning Method No. 20 - Four-Step Alkaline Cleaning and Acidic Descaling (With Inhibited Phosphoric Acid)). |
2 . | Equipment. |
Subtask 70-21-20-110-381 |
C. | The following equipment is required for the application of this process: |
(1) | Safety equipment and devices which are standard equipment in surface treatment shops such as: eye bath, emergency showers, protective clothing against electroplating products and means for neutralizing acid or alkaline splashing. |
(2) | Processing plant for neutralizing waste and used solutions. |
(3) | Efficient ventilation system for extracting and neutralizing vapors. |
(4) | An alkaline degreasing tank made of stainless steel with a heating coil that is capable of heating the solution to 200°F (93°C). |
(5) | A water rinse tank made from stainless steel (or a carbon steel tank with a polypropylene liner) and a water spray gun, used after the degreasing bath. |
(6) | An acid stripping tank made of stainless steel with a heating coil that is capable of heating the solution to 185°F (85°C). |
(7) | A water rinse tank made from stainless steel (or a carbon steel tank with a polypropylene lining) and water spray gun, used after the acid stripping bath. |
(8) | A permanganate cleaning tank made of stainless steel with a heating coil capable of heating the solution to 180°F (82°C). |
(9) | A water rinse tank made from stainless steel (or a carbon steel tank with a polypropylene lining) and a water spray gun, used after the alkaline permanganate bath. |
(10) | A phosphoric acid cleaning tank made of stainless steel (or a carbon steel tank with a polypropylene lining). |
(11) | A water rinse tank made from stainless steel (or a carbon steel tank with a polypropylene lining) and water spray gun, used after the phosphoric acid bath. |
(12) | A hot water rinse tank made from stainless steel (or a carbon steel tank with polypropylene lining) that can increase the temperature of the solution to 200°F (93°C). |
3 . | Materials. |
Subtask 70-21-20-110-382 |
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4 . | Procedure. |
Subtask 70-21-20-110-383 |
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D. | In case of excessive dirt, pre-clean the part. Refer to TASK 70-21-01-110-001 (70-21-01, Cleaning Method No. 1 - Solvent Degreasing) or TASK 70-21-22-110-042 (70-21-22, Cleaning Method No. 22 Light Duty Aqueous Cleaning (method No. 1)). |
E. | Mask all areas that have thermal spray wear coatings including T400, T800, tungsten carbide/cobalt, chrome carbide/nickel chrome, and seal teeth aluminum oxide topcoat. Refer to TASK 70-18-01-330-801, Masking Method No. 1 - Masking With Chemical Maskant, unless otherwise stated in the service document. |
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F. | Immerse the part in a tank containing one of the alkaline degreasing/rust removing solutions and maintain the solution at the specified temperature. The alkaline degreasing/rust removing solutions are listed in Table 1 in Subtask 70-21-20-110-382, Materials. |
Duration: 15 to 60 minutes. |
G. | Rinse by spraying with a water jet and by immersion in water at room temperature. |
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H. | Immerse the part in a tank containing one of the acid stripping solutions and maintain the solution at the specified temperature. The acid stripping solutions are listed in Table 2 in Subtask 70-21-20-110-382, Materials. |
Duration: 15 to 30 minutes. |
I. | Rinse by spraying with a water jet and by immersion in water at room temperature. |
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J. | Immerse the part in a tank containing one of the alkaline permanganate solutions and maintain the solution at the specified temperature. The alkaline permanganate solutions are listed in Table 3 in Subtask 70-21-20-110-382, Materials. |
Duration: 15 to 30 minutes. |
K. | Rinse by spraying with a water jet and immersion in water at room temperature. |
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L. | Immerse the part in a tank containing one of the phosphoric acid solutions with inhibitor listed in Table 4 in Subtask 70-21-20-110-382, Materials. |
Duration: 15 to 30 minutes. |
M. | Rinse by spraying with a water jet and by immersion in water at room temperature. |
N. | Rinse by immersion in hot water at minimum 150ºF (66ºC). |
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O. | Dry the part by one of the following two methods. |
(1) | Flash dry the part as follows: |
(a) | Keep the part submerged until the part reaches a temperature sufficient to provide for flash drying. |
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(b) | Remove the part from the water. The part will flash dry as soon as it is removed from the water. Use repositioning, suction, blotting with a clean, absorbent material, or by blowing off with an oil and water filtered shop air gun to remove excess water. |
(2) | You can substitute drying the part in an air re-circulating oven for the dwell time in the hot water. |
(a) | Remove the part from the water. You can remove excess water by repositioning, suction, blotting with a clean absorbent material, or blowing the water off with an oil and water filtered shop air gun. |
(b) | Move the part to the oven and dry at 200°F ± 25°F (93°C ± 14°C) until the part reaches the oven temperature and all traces of surface water are removed. |
5 . | Quality Assurance. |
Subtask 70-21-20-110-384 |
P. | Visually check the part and assure that all traces of oxide on the part have been removed. |
Q. | If oxides are still present on the part after this cleaning, use TASK 70-21-04-120-E01 , Dry Abrasive Blast Cleaning - Method No. 4E, to remove the contaminants. |
6 . | Ultrasonic Agitation of the Solution(s). |
Subtask 70-21-20-110-536 |
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R. | Ultrasonic agitation of the solution can be used to increase the efficiency of the cleaning process. This subtask gives process parameters for ultrasonic agitation. Refer also to Subtask 70-21-20-110-536 for safety precautions and general information. |
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S. | Processing tank with temperature control. |
(1) | The ultrasonic tank should be made of stainless steel and be equipped with either a heat exchanger or heating coil capable of controlling the working solution at the minimum and the maximum operating temperature established. |
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(2) | The tank should be clearly labeled with the minimum operating level. |
(3) | The tank must be provided with an automatic timer interlock to shut off the ultrasonic equipment, a low solution level shut-off interlock, or with a minimum solution level marker. The tank should be identified and clearly labeled with the chemical contents, power density, frequency of the ultrasonic unit, and rated capacity in gallons (or liters). |
T. | Generator requirements. |
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(1) | The generator must be a fixed power rating and not be adjustable by the operator. |
(a) | The ultrasonic tank must be operated at a frequency between 25 and 80 kHz and shall be maximum 80 watts/gallons (21.1 watts per liter) power density. |
(b) | Transducers should be equipped with High Sweep Modulation capability for optimum cleaning efficiency. The sweep range should be 0.5 to 4 kHz. |
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U. | Ultrasonic cleaning units must be checked for operating efficiency periodically, at a frequency depending on the usage, with a suitable method. |
(1) | Alternative Method: |
(a) | Use Heavy Duty Reynolds Aluminum Foil, or similar aluminum foil, 0.009 inch (0.023 centimeter) in thickness. |
(b) | Fabricate a foil sheet such that when placed vertically in the tank, foil spans the entire depth and the longest width of tank dimensions. |
1 | Bend edges of foil for rigidity (to prevent foil from bending when placing in solution/tank). |
2 | If the span is too large for one sheet of foil, fabricate a stainless-steel light rod framework (such as welding rod) to attach the foil. |
(c) | Cleaning solution should be that as specified by the cleaning procedure. If the cleaning solution reacts with aluminum foil, water should be used. |
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(d) | Degas cleaning solution in an ultrasonic tank for the required time (approximately 15 minutes) for maximum cavitation intensity. |
(e) | Immerse aluminum foil vertically into an ultrasonic tank slow and gently to minimize disturbing the sheet. |
(f) | Keep aluminum foil immersed in an active ultrasonic tank for one minute. |
(g) | Remove aluminum foil sheet vertically slow and gently to minimize disturbing the sheet. |
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(2) | Alternative Method: |
(a) | If contamination by aluminum foil debris is not desired, the foil must be immersed in a suitability sized glass beaker that contains water. |
(b) | Degas the water in the beaker for 10 minutes for maximum cavitation intensity. |
(c) | Put the beaker in the solution and minimize the attenuation of the ultrasonic vibrations. |
(d) | Keep the foil immersed in the water in the beaker for 90 seconds of operation. |
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(3) | Acceptance Criteria. Foil must have a complete and even distribution pattern of pockmarks or indentations throughout entire sheet. Some tiny through holes may be created, and are acceptable if there is a relatively even distribution of these holes. |
(4) | Rejection. If foil patterns include lack of or light pockmark patters, inconsistent and uneven pockmark distribution, and large through hole(s) in localized areas, the bath cannot be used for the cleaning process. |
(5) | Foil test must be repeated after: |
(a) | The first installation, upgrades, or repair of ultrasonic equipment (comprised of transducers, controls, wiring, power unit). |
(b) | The first installation of the immersion tank. |
(c) | Repair on the wetted walls of the immersion tank. |
V. | Fixture requirements. |
(1) | The parts must be suspended in the tank completely independent of the tank sidewalls, tank bottom, or transducer surface. |
(2) | The fixtures can be hung from the lip of the tank if the points of contact are insulated or dampened from the ultrasonic transducer or the tank. |
(3) | Parts should be placed at least 2 inches (50.8 mm) from the ultrasonic transducers or the tank walls and bottom. Parts shall never be closer than 1 inch (25.4 mm) from the tank walls and bottom. They shall be submerged at least 1 inch (25.4 mm) below the top of the solution. If the parts have holes and/or cavities, the parts must be rotated to be sure that all holes and/or cavities are filled with cleaning solution and all the air is removed. |
(4) | Part-to-part or metal (rack)-to-part contact during ultrasonic cleaning is not permitted. If more than one part is cleaned at a time, it is recommended that you use fixtures to put the parts in position so that it is impossible for the parts to touch one another during the ultrasonic agitation. |
(5) | Fixtures should be designed to maximize mesh opening size. |
(6) | Fixtures should be fabricated from plastic or plastic-coated metal to minimize the risk of part damage at the point of contact with the fixture. |
W. | Deleted. |
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X. | Process requirements. |
(1) | For every new part to be cleaned with the assistance of ultrasonic, the 1st article must be run 4X (4 times) the maximum time based on the historical time needed to clean the part using the standard cleaning process. This should include the time in each tank of the cleaning process that is to be equipped with ultrasonic capability. All standard non-destructive inspections required for the part should be completed before and shall be completed after the 4X cleaning test to assure no damage or cracks are caused by the cleaning process. |
(2) | A demonstration of the cleaning procedure is necessary on a stock loss coupon of the alloy in question. This demonstration must use 4X (4 times) the maximum time based on the historical time needed to clean the part using the standard cleaning process. This should include the time in each tank of the cleaning process that is to be equipped with ultrasonic capability, maximum temperature and concentration of solution developed for the application. Stock loss testing should be performed according to ARP1755. |
(3) | Filtration and cleanliness requirements should be established for the cleaning solutions. |